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Functionalized nanocellulose based adsorbents for dye removal from wastewater

Yıl 2021, Cilt 22, Sayı 1, 148 - 160, 12.05.2021
https://doi.org/10.17474/artvinofd.830601

Öz

In recent years, agricultural and industrial activities have gradually increased with the increasing population worldwide. Many pollutants, such as organic substances, inorganic anions, toxic heavy metals, toxic gases etc., generated during these activities are released into the environment and cause significant pollution problems, especially in water. Therefore, environmentally friendly and cost-effective treatment technologies are needed. The adsorption process used in waste water is one of the environmentally friendly purification technologies. Cellulosic materials obtained from various natural sources can be used as adsorbents. The adsorption capacity of organic pollutants and heavy metal ions in wastewater is affected by chemical processes, and it is known that modified cellulose exhibits higher adsorption capacity than unmodified cellulose. In this review, the adsorption capacities of various nanocellulose-based adsorbents, especially in the removal of dyes in wastewater, and the FTIR and SEM analyzes used in the characterization of the structures of these adsorbents after modifications were examined. Nanocellulose-based adsorbents appear to exhibit good potential in removing dyes in the waste water. It is thought that cheap and more effective cellulose-based adsorbents can be developed with modifications to minimize environmental pollution.

Kaynakça

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  • Alemdar A, Sain M (2008) Isolation and characterization of nanofibers from agricultural residues – wheat straw and soy hulls. Bioresource Technology 99(6):1664–1671
  • Anonim (2013) NanoHeal. http://www.pfi.no/New-Biomaterials/Projects/NanoHeal. Erişim: 15.10.2014.
  • Aravindhan R, Fathima NN, Rao JR, Nair BU (2007) Equilibrium and thermodynamic studies on the removal of basic black dye using calcium alginate beads. Colloids and Surfaces A: Physicochemical and Engineering Aspects 299:232–238
  • Aulin C, Ahola S, Josefsson P, Nishino T, Hirose Y, Österberg M, Wagberg L (2009) Nanoscale cellulose films with different crystallinities and mesostructures—their surface properties and interaction with water. Langmuir 25(13):7675–7685
  • Batmaz R, Mohammed N, Zaman M, Minhas G, Berry RM, Tam KC (2014) Cellulose nanocrystals as promising adsorbents for the removal of cationic dyes. Cellulose 21(3):1655-1665
  • Beyki MH, Bayat M, Shemirani F (2016) Fabrication of core–shell structured magnetic nanocellulose base polymeric ionic liquid for effective biosorption of Congo red dye. Bioresource Technology 218:326–334
  • Bharimalla AK, Deshmukh SP, Vigneshwaran N, Patil PG, Prasad V (2017) Nanocellulose-polymer composites for applications in food packaging: current status, future prospects and challenges. Polymer-Plastıcs Technology And Engıneerıng 56:805-823
  • Bhattacharyya R, Ray SK (2015) Removal of congo red and methyl violet from water using nano clay filled composite hydrogels of poly acrylic acid and polyethylene glycol. Chemical Engineering Journal 260:269-283
  • Camcıoğlu Ş (2010) Su bazlı boya üretim tesislerinin atıksularının arıtılmasında genelleştirilmiş minimum değişmeli algoritma ile pH kontrolü. Ankara Üniversitesi, Fen Bilimleri Enstitüsü, Yüksek Lisans Tezi, Ankara
  • Cao X, Chen Y, Chang PR, Muir AD, Falk D (2008) Starch-based nanocomposites reinforced with flax cellulose Nanocrystals. XPRESS Polymer Letters 2(7):502-510
  • Chan CH, Chia CH, Zakaria S, Sajab MS, Chin SX (2015) Cellulose nanofibrils: a rapid adsorbent for the removal of methylene blue. RSC Advances 5:18204–18212
  • Chan HC, Chia CH, Zakaria S, Ahmad I, Dufresne A (2013) Production and characterization of cellulose and nano-crystalline from kenaf core wood. BioResources 8:785-794
  • Chen W, Li Q, Wang Y, Xin YX, Zeng J, Yu H, Liu Y, Li J (2014) Comparative study of aerogels obtained from differently prepared nanocellulose fibers. ChemSusChem 7:154–161
  • Chong KY, Chia CH, Zakaria S, Sajab MS, Chook SW, Khiew PS (2015) CaCO3- decorated cellulose aerogel for removal of Congo Red from aqueous solution. Cellulose, 22(4):2683–2691
  • Crini G (2006) Non-conventional low-cost adsorbents for dye removal: a review. Bioresource Technology 97:1061–1085
  • Deng C, Liu J, Zhou W, Zhang YK, Du KF, Zhao ZM (2012) Fabrication of spherical cellulose/carbon tubes hybrid adsorbent anchored with welan gum polysaccharide and its potential in adsorbing methylene blue. Chemical Engineering Journal 200–202:452–458
  • Dufresne A (2008) Polysaccharide nano crystal reinforced nanocomposites. Canadian Journal of Chemistry 86(6):484-494
  • Dural MU, Cavas L, Papageorgiou SK, Katsaros FK (2011) Methylene blue adsorption on activated carbon prepared from Posidonia oceanica (L.) dead leaves: kinetics and equilibrium studies. Chemical Engineering Journal 168:77–85
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  • Iwamoto S, Nakagaito AN, Yano H (2007) Nano-fibrillation of pulp fibers for the processing of transparent nanocomposites. Applied Physics A 89(2):461–466
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  • Jin L, Sun Q, Xu Q, Xu Y (2015a) Adsorptive removal of anionic dyes from aqueous solutions using microgel based on nanocellulose and polyvinylamine. Bioresource Technology 197:348–355
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Atık sularda boya giderimi için fonsiyonellenmiş nanoselüloz esaslı adsorbanlar

Yıl 2021, Cilt 22, Sayı 1, 148 - 160, 12.05.2021
https://doi.org/10.17474/artvinofd.830601

Öz

Son yıllarda, dünya genelinde artan nüfus ile birlikte tarımsal ve endüstriyel faaliyetler giderek artmıştır. Bu faaliyetler sırasında ortaya çıkan organik maddeler, inorganik anyonlar, toksik ağır metaller, zehirli gazlar vb. birçok kirletici çevreye salınmakta ve özellikle sularda önemli derecede kirlilik sorunlarına yol açmaktadır. Bu nedenle çevre dostu ve uygun maliyetli arıtma teknolojilerine ihtiyaç duyulmaktadır. Atık sularda kullanılan adsorpsiyon işlemi çevre dostu arıtma teknolojilerinden biridir. Çeşitli doğal kaynaklardan elde edilebilen selülozik maddeler adsorbanlar olarak kullanılabilmektedir. Atık sularda bulunan organik kirleticiler ve ağır metal iyonlarının adsorpsiyon kapasiteleri kimyasal işlemlerden etkilenmekte olup, modifiye edilmiş selülozun modifiye edilmemiş selüloza göre daha yüksek adsorpsiyon kapasitesi sergilediği bilinmektedir. Bu derlemede, literatürde yer alan çeşitli nanoselüloz esaslı adsorbanların, özellikle atık sularda bulunan boyaların uzaklaştırılmasında sergiledikleri adsorpsiyon kapasiteleri ve bu adsorbanların modifikasyonları sonrasında yapılarının karakterizasyonunda kullanılan FTIR ve SEM analizleri incelenmiştir. Nanoselüloz esaslı adsorbanların atık sulardaki boyaların uzaklaştırılmasında iyi bir potansiyel sergilediği görülmektedir. Çevre kirliliğini minimuma indirmek için ucuz ve daha etkili selüloz esaslı adsorbanların modifikasyonlarla geliştirilebileceği düşünülmektedir.

Kaynakça

  • Abe K, Iwamoto S, Yano H (2007) Obtaining cellulose nanofibers with a uniform width of 15 nm from wood. Biomacromolecules 8(10):3276–3278
  • Alemdar A, Sain M (2008) Isolation and characterization of nanofibers from agricultural residues – wheat straw and soy hulls. Bioresource Technology 99(6):1664–1671
  • Anonim (2013) NanoHeal. http://www.pfi.no/New-Biomaterials/Projects/NanoHeal. Erişim: 15.10.2014.
  • Aravindhan R, Fathima NN, Rao JR, Nair BU (2007) Equilibrium and thermodynamic studies on the removal of basic black dye using calcium alginate beads. Colloids and Surfaces A: Physicochemical and Engineering Aspects 299:232–238
  • Aulin C, Ahola S, Josefsson P, Nishino T, Hirose Y, Österberg M, Wagberg L (2009) Nanoscale cellulose films with different crystallinities and mesostructures—their surface properties and interaction with water. Langmuir 25(13):7675–7685
  • Batmaz R, Mohammed N, Zaman M, Minhas G, Berry RM, Tam KC (2014) Cellulose nanocrystals as promising adsorbents for the removal of cationic dyes. Cellulose 21(3):1655-1665
  • Beyki MH, Bayat M, Shemirani F (2016) Fabrication of core–shell structured magnetic nanocellulose base polymeric ionic liquid for effective biosorption of Congo red dye. Bioresource Technology 218:326–334
  • Bharimalla AK, Deshmukh SP, Vigneshwaran N, Patil PG, Prasad V (2017) Nanocellulose-polymer composites for applications in food packaging: current status, future prospects and challenges. Polymer-Plastıcs Technology And Engıneerıng 56:805-823
  • Bhattacharyya R, Ray SK (2015) Removal of congo red and methyl violet from water using nano clay filled composite hydrogels of poly acrylic acid and polyethylene glycol. Chemical Engineering Journal 260:269-283
  • Camcıoğlu Ş (2010) Su bazlı boya üretim tesislerinin atıksularının arıtılmasında genelleştirilmiş minimum değişmeli algoritma ile pH kontrolü. Ankara Üniversitesi, Fen Bilimleri Enstitüsü, Yüksek Lisans Tezi, Ankara
  • Cao X, Chen Y, Chang PR, Muir AD, Falk D (2008) Starch-based nanocomposites reinforced with flax cellulose Nanocrystals. XPRESS Polymer Letters 2(7):502-510
  • Chan CH, Chia CH, Zakaria S, Sajab MS, Chin SX (2015) Cellulose nanofibrils: a rapid adsorbent for the removal of methylene blue. RSC Advances 5:18204–18212
  • Chan HC, Chia CH, Zakaria S, Ahmad I, Dufresne A (2013) Production and characterization of cellulose and nano-crystalline from kenaf core wood. BioResources 8:785-794
  • Chen W, Li Q, Wang Y, Xin YX, Zeng J, Yu H, Liu Y, Li J (2014) Comparative study of aerogels obtained from differently prepared nanocellulose fibers. ChemSusChem 7:154–161
  • Chong KY, Chia CH, Zakaria S, Sajab MS, Chook SW, Khiew PS (2015) CaCO3- decorated cellulose aerogel for removal of Congo Red from aqueous solution. Cellulose, 22(4):2683–2691
  • Crini G (2006) Non-conventional low-cost adsorbents for dye removal: a review. Bioresource Technology 97:1061–1085
  • Deng C, Liu J, Zhou W, Zhang YK, Du KF, Zhao ZM (2012) Fabrication of spherical cellulose/carbon tubes hybrid adsorbent anchored with welan gum polysaccharide and its potential in adsorbing methylene blue. Chemical Engineering Journal 200–202:452–458
  • Dufresne A (2008) Polysaccharide nano crystal reinforced nanocomposites. Canadian Journal of Chemistry 86(6):484-494
  • Dural MU, Cavas L, Papageorgiou SK, Katsaros FK (2011) Methylene blue adsorption on activated carbon prepared from Posidonia oceanica (L.) dead leaves: kinetics and equilibrium studies. Chemical Engineering Journal 168:77–85
  • Eriksen Ø, Syverud K, Gregersen Ø (2008) The use of microfibrillated cellulose produced from kraft pulp as strength enhancer in tmp paper. Nordic Pulp & Paper Research Journal 23(3):299-304
  • Fabio PG, Nuno HCS, Trovatti E, Serafim LS, Duarte MF, Silvestre AJD, Neto CP, Carmen SRF (2013) Production of bacterial cellulose by Gluconacetobacter sacchari using dry olive mill residue. Biomass Bioenergy 55:205-211
  • Freundlich H (1906) Uber die adsorption in lösungen. Zeitschrift für Physikalische Chemie 57:385–470
  • Gama M, Gatenholm P, Klemm D (2012) Bacterial nanocellulose: a sophisticated multifunctional material. CRC Press, Boca Raton, p 304
  • Gómez CH, Serpa A, Velásquez-Cock J, Gañán P, Castro C, Vélez L, Zuluaga R (2016) Vegetable nanocellulose in food science: a review. Food Hydrocolloids 57:178-186
  • Habibi Y, Lucia LA, Rojas OJ (2010) Cellulose nanocrystals: chemistry, self-assembly, and applications. Chemichal Reviews 110:3479–3500
  • He X, Male KB, Nesterenko PN, Brabazon D, Paull B, Luong JHT (2013) Adsorption and desorption of methylene blue on porous carbon monoliths and nanocrystalline cellulose. ACS Applied Materials & Interfaces 5:8796–8804
  • Hubbe MA, Heitmann JA (2007) Review of factors affecting the release of water from cellulosic fibers during paper manufacture. BioRessources 2(3):500-533
  • Ifuku S, Nogi M, Abe K, Handa K, Nakatsubo F, Yano H (2007) Surface modification of bacterial cellulose nanofibres for property enhancement of optically transparent composites: dependence on acetyl-group DS. Biomacromolecules 8:1973–1978
  • Ioelovıch M, Leykin A (2004) Nanocellulose and its application. Journal "Scientific Israel – Technological Advantages" 6(3):17-24
  • Iwamoto S, Nakagaito AN, Yano H (2007) Nano-fibrillation of pulp fibers for the processing of transparent nanocomposites. Applied Physics A 89(2):461–466
  • Jin L, Li W, Xu Q, Sun Q (2015b) Amino-functionalized nanocrystalline cellulose as an adsorbent for anionic dyes. Cellulose 22:2443–2456.
  • Jin L, Sun Q, Xu Q, Xu Y (2015a) Adsorptive removal of anionic dyes from aqueous solutions using microgel based on nanocellulose and polyvinylamine. Bioresource Technology 197:348–355
  • Kabay N (2002) Yeni O,O’-dihidroksi azo boyarmaddelerin metal komplekslerinin sentezi ve yapılarının aydınlatılması. Pamukkale Üniversitesi, Fen Bilimleri Enstitüsü, Yüksek Lisans Tezi, Denizli
  • Karim Z, Mathew AP, Grahn M, Mouzonb J, Oksmana K (2014) Nanoporous membranes with cellulose nanocrystals as functional entity in chitosan: removal of dyes from water. Carbohydrate Polymers 112:668–676
  • Kayranli B (2011) Adsorption of textile dyes onto iron based waterworks sludge from aqueous solution: isotherm, kinetic and thermodynamic study. Chemical Engineering Journal 173:782–791
  • Klemm D, Kramer F, Moritz S, Lindström T, Ankerfors M, Gray D, Dorris A (2011) Nanocelluloses: a new family of nature-based materials. Angewandte Chemie International Edition 50(24):5438–5466
  • Klemm D, Schumann D, Kramer F, Hessler N, Hornung M, Schmauder HP, Marsch S (2006) Nanocelluloses as ınnovative polymers in research and application. Advances in Polymer Science 205:49-96
  • Langmuir I (1918) The adsorption of gases on plane surfaces of glass, mica and platinum. Journal of the American Chemical Society, 40:1361–1403
  • Lavoine N, Desloges I, Dufresne A, Bras J (2012) Microfibrillated cellulose – its barrier properties and applications in cellulosic materials: a review. Carbohydrate Polymers 90:735–764
  • Liang CY, Marchessault RH (1959) Infrared spectra of crystalline polysaccharides. I. hydrogen bonds in native celluloses. Journal of Polymer Science 37:385- 395
  • Lin N, Dufresne A (2014) Nanocellulose in biomedicine: current status and futureprospect. European Polymer Journal 59:302–325
  • Liu P, Sehaqui H, Tingaut P, Wichser A, Oksman K, Mathew AP (2014) Biobased nanomaterials for capturing silver ions (Ag+) from water via surface adsorption. Cellulose 21:449–461
  • Ma H, Burger C, Hsiao BS, Chu B (2011) Nanofibrous microfiltration membrane based on cellulose nanowhiskers. Biomacromolecules 13(1):180–186
  • Mahfoudhi N, Boufi S (2017) Nanocellulose as a novel nanostructured adsorbent for environmental remediation: a review. Cellulose 24:1171–1197
  • Missoum K, Belgacem MN, Bras J (2013) Nanofibrillated cellulose surface modification: a review. Materials 6:1745–1766
  • Mohammed N, Grishkewich N, Berry RM, Tam KC (2015) Cellulose nanocrystal–alginate hydrogel beads as novel adsorbents for organic dyes in aqueous solutions. Cellulose 22:3725–3738
  • Murphy V, Hughes H, McLoughlin P (2008) Comparative study of chromium biosorption by red, green and brown seaweed biomass. Chemosphere 70:1128–1134
  • Pääkko M, Ankerfors M, Kosonen H, Nykänen A, Ahola S, Österberg M, Ruokolainen J, Laine J, Larsson PT, Ikkala O, Lindström T (2007) Enzymatic hydrolysis combined with mechanical shearing and high-pressure homogenization for nanoscale cellulose fibrils and strong gels. Biomacromolecules 8(6):1934-1941
  • Pahimanolis N, Hippi U, Johansson LS, Saarinen T, Houbenov N, Ruokolainen J, Seppala J (2011) Surface functionalization of nanofibrillated cellulose using click-chemistry approach in aqueous media. Cellulose, 18:1201–1212
  • Pearce CI, Lloyd JR, Guthrie JT (2003) The removal of colour from textile wastewater using whole bacterial cells: a review. Dyes Pigment 58:179–196
  • Pei A, Butchosa N, Berglund LA, Zhou Q (2013) Surface quaternized cellulose nanofibrils with high water absorbency and adsorption capacity for anionic dyes. Soft Matter 9:2047–2055
  • Piccin JS, Gomes CS, Feris LA, Gutterres M (2012) Kinetics and isotherms of leather dye adsorption by tannery solid waste. Chemical Engineering Journal 183:30–38
  • Poyraz B, Arslan R, Akıncı A, Tozluoğlu A (2018) Chemical and morpholgical analysis of modified nanocellulose. Artvin Coruh University Journal of Forestry Faculty 19(1):39-47
  • Qiao H, Zhou Y, Yu F, Wang E, Min Y, Huang Q, Pang L, Ma T (2015) Effective removal of cationic dyes using carboxylate-functionalized cellulose nanocrystals. Chemosphere 141:297-303
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Ayrıntılar

Birincil Dil Türkçe
Konular Orman Mühendisliği
Yayınlanma Tarihi Mayıs
Bölüm Derleme
Yazarlar

Recai ARSLAN (Sorumlu Yazar)
DÜZCE ÜNİVERSİTESİ, ORMAN FAKÜLTESİ
0000-0003-3839-4861
Türkiye


Ayhan TOZLUOĞLU
DÜZCE ÜNİVERSİTESİ, ORMAN FAKÜLTESİ
0000-0002-1828-9450
Türkiye


Selva SERTKAYA
DÜZCE ÜNİVERSİTESİ, ORMAN FAKÜLTESİ
0000-0002-0490-1821
Türkiye


Hakan FİDAN
İZMİR KATİP ÇELEBİ ÜNİVERSİTESİ, ORMAN FAKÜLTESİ
0000-0003-3361-8336
Türkiye


Sibel KÜÇÜK
DÜZCE ÜNİVERSİTESİ
0000-0002-7852-5128
Türkiye

Yayımlanma Tarihi 12 Mayıs 2021
Yayınlandığı Sayı Yıl 2021, Cilt 22, Sayı 1

Kaynak Göster

Bibtex @derleme { artvinofd830601, journal = {Artvin Çoruh Üniversitesi Orman Fakültesi Dergisi}, issn = {2146-1880}, eissn = {2146-698X}, address = {}, publisher = {Artvin Çoruh Üniversitesi}, year = {2021}, volume = {22}, pages = {148 - 160}, doi = {10.17474/artvinofd.830601}, title = {Atık sularda boya giderimi için fonsiyonellenmiş nanoselüloz esaslı adsorbanlar}, key = {cite}, author = {Arslan, Recai and Tozluoğlu, Ayhan and Sertkaya, Selva and Fidan, Hakan and Küçük, Sibel} }
APA Arslan, R. , Tozluoğlu, A. , Sertkaya, S. , Fidan, H. & Küçük, S. (2021). Atık sularda boya giderimi için fonsiyonellenmiş nanoselüloz esaslı adsorbanlar . Artvin Çoruh Üniversitesi Orman Fakültesi Dergisi , 22 (1) , 148-160 . DOI: 10.17474/artvinofd.830601
MLA Arslan, R. , Tozluoğlu, A. , Sertkaya, S. , Fidan, H. , Küçük, S. "Atık sularda boya giderimi için fonsiyonellenmiş nanoselüloz esaslı adsorbanlar" . Artvin Çoruh Üniversitesi Orman Fakültesi Dergisi 22 (2021 ): 148-160 <http://ofd.artvin.edu.tr/tr/pub/issue/62326/830601>
Chicago Arslan, R. , Tozluoğlu, A. , Sertkaya, S. , Fidan, H. , Küçük, S. "Atık sularda boya giderimi için fonsiyonellenmiş nanoselüloz esaslı adsorbanlar". Artvin Çoruh Üniversitesi Orman Fakültesi Dergisi 22 (2021 ): 148-160
RIS TY - JOUR T1 - Atık sularda boya giderimi için fonsiyonellenmiş nanoselüloz esaslı adsorbanlar AU - Recai Arslan , Ayhan Tozluoğlu , Selva Sertkaya , Hakan Fidan , Sibel Küçük Y1 - 2021 PY - 2021 N1 - doi: 10.17474/artvinofd.830601 DO - 10.17474/artvinofd.830601 T2 - Artvin Çoruh Üniversitesi Orman Fakültesi Dergisi JF - Journal JO - JOR SP - 148 EP - 160 VL - 22 IS - 1 SN - 2146-1880-2146-698X M3 - doi: 10.17474/artvinofd.830601 UR - https://doi.org/10.17474/artvinofd.830601 Y2 - 2021 ER -
EndNote %0 Artvin Çoruh Üniversitesi Orman Fakültesi Dergisi Atık sularda boya giderimi için fonsiyonellenmiş nanoselüloz esaslı adsorbanlar %A Recai Arslan , Ayhan Tozluoğlu , Selva Sertkaya , Hakan Fidan , Sibel Küçük %T Atık sularda boya giderimi için fonsiyonellenmiş nanoselüloz esaslı adsorbanlar %D 2021 %J Artvin Çoruh Üniversitesi Orman Fakültesi Dergisi %P 2146-1880-2146-698X %V 22 %N 1 %R doi: 10.17474/artvinofd.830601 %U 10.17474/artvinofd.830601
ISNAD Arslan, Recai , Tozluoğlu, Ayhan , Sertkaya, Selva , Fidan, Hakan , Küçük, Sibel . "Atık sularda boya giderimi için fonsiyonellenmiş nanoselüloz esaslı adsorbanlar". Artvin Çoruh Üniversitesi Orman Fakültesi Dergisi 22 / 1 (Mayıs 2021): 148-160 . https://doi.org/10.17474/artvinofd.830601
AMA Arslan R. , Tozluoğlu A. , Sertkaya S. , Fidan H. , Küçük S. Atık sularda boya giderimi için fonsiyonellenmiş nanoselüloz esaslı adsorbanlar. AÇÜOFD. 2021; 22(1): 148-160.
Vancouver Arslan R. , Tozluoğlu A. , Sertkaya S. , Fidan H. , Küçük S. Atık sularda boya giderimi için fonsiyonellenmiş nanoselüloz esaslı adsorbanlar. Artvin Çoruh Üniversitesi Orman Fakültesi Dergisi. 2021; 22(1): 148-160.
IEEE R. Arslan , A. Tozluoğlu , S. Sertkaya , H. Fidan ve S. Küçük , "Atık sularda boya giderimi için fonsiyonellenmiş nanoselüloz esaslı adsorbanlar", Artvin Çoruh Üniversitesi Orman Fakültesi Dergisi, c. 22, sayı. 1, ss. 148-160, May. 2021, doi:10.17474/artvinofd.830601
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